Fabrication of solid strong bases with a molecular-level dispersion of lithium sites and high basic catalytic activity.

نویسندگان

  • Lin-Bing Sun
  • Jie Shen
  • Feng Lu
  • Xiao-Dan Liu
  • Li Zhu
  • Xiao-Qin Liu
چکیده

New solid strong bases were fabricated at room temperature by grafting lithium-containing molecular precursors onto β-cyclodextrin. The solid bases show strong basicity with a molecular-level dispersion of lithium sites, which are highly active in transesterification reactions and impossible to realize through the traditional high-temperature method.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Molecular Engineering of the Geobacillus stearothermophilus α-Amylase and Cel5E from Chlostridium thermocellim; In Silico Approach

Background: Considering natural thermal stability, Geobacillus stearothermophilus amylase and Cel5E from Clostridium thermocellum are good candidates for industrial applications. To be compatible with the industrial applications, this enzyme should be stable in the high temperatures, so any improvement in their thermal stability is valuable.Objectives: Us...

متن کامل

Catalytic Performance and Characterization of Promoted K-La/ZSM-5 Nanocatalyst for Biodiesel Production

The promoted K-La nanocatalysts supported on ZSM-5 zeolite were prepared via wetness impregnation method and tested for biodiesel production from soybean oil. The effects of different weight percentage of La, loading of K as a promoter and calcination conditions on structure and activity of catalyst were investigated. Results showed that the supported catalyst containing 7wt.% of La was pro...

متن کامل

Novel Schiff Bases of Pyrrole: Synthesis, Experimental and Theoretical Characterizations, Fluorescent Properties and Molecular Docking

Some new Schiff-base compounds based on pyrrole were synthesized by the reaction of 2-amino-1-methyl-4,5-diphenyl-1H-pyrrole-3-carbonitrile (1)with aromatic aldehydes (2a-2e) in ethanol/acetic acid at room temperature. The structures of the Schiff bases were characterized by full spectral data. The fluorescence emission intensity of the Schiff bases has bee...

متن کامل

Synthesis and catalytic properties of nano CuO prepared by soft chemical method

Well faceted CuO nanoparticles, were synthesized by thermal-assisted dissociation method at reflux temperature in a short period of time. A possible mechanism for synthesis of such highly pure and stable nanoparticles is tentatively proposed by FT-IR study. The large surface area and rich exposed active sites are expected to endow such nanoparticles with excellent performances in catalysis as d...

متن کامل

Synthesis and catalytic properties of nano CuO prepared by soft chemical method

Well faceted CuO nanoparticles, were synthesized by thermal-assisted dissociation method at reflux temperature in a short period of time. A possible mechanism for synthesis of such highly pure and stable nanoparticles is tentatively proposed by FT-IR study. The large surface area and rich exposed active sites are expected to endow such nanoparticles with excellent performances in catalysis as d...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 50 77  شماره 

صفحات  -

تاریخ انتشار 2014